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Hetero-metallic, functionalizable polyoxomolybdate clusters via a “top-down” synthetic method

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Abstract

Two bi-metallic, organophosphonate-stabilised sandwich-type polyoxomolybdate clusters, [Mo6Cu4O16(OH)2(C4H9PO3)4(C5H5N)2 (CH3O)4(H2O)]2− and [Mo7Cu7O19(OH)(CH3O)7(C4H9PO3)6(C5H5N)2]2−, are reported. These compounds are accessed via the “top-down” in situ disassembly of the [Mo6O19]2− Lindqvist species into reactive oligomers, followed by subsequent reassembly with polynuclear CuII assemblies to form the reported compounds.

Graphical abstract: Hetero-metallic, functionalizable polyoxomolybdate clusters via a “top-down” synthetic method

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Publication details

The article was received on 15 Jul 2017, accepted on 01 Sep 2017 and first published on 01 Sep 2017


Article type: Communication
DOI: 10.1039/C7CC05498J
Citation: Chem. Commun., 2017, Advance Article
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    Hetero-metallic, functionalizable polyoxomolybdate clusters via a “top-down” synthetic method

    C. Healy, B. Twamley, M. Venkatesan, S. Schmidt, T. Gunnlaugsson and W. Schmitt, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC05498J

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