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Issue 83, 2017
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Silver-mediated oxidative C–H difluoromethylation of phenanthridines and 1,10-phenanthrolines

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Abstract

A silver-mediated oxidative difluoromethylation of phenanthridines and 1,10-phenanthrolines with TMSCF2H is disclosed. This C–H difluoromethylation of N-containing polycyclic aromatics constitutes an efficient method for the regioselective synthesis of difluoromethylated N-heterocycles.

Graphical abstract: Silver-mediated oxidative C–H difluoromethylation of phenanthridines and 1,10-phenanthrolines

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Publication details

The article was received on 14 Jul 2017, accepted on 01 Oct 2017 and first published on 02 Oct 2017


Article type: Communication
DOI: 10.1039/C7CC05411D
Citation: Chem. Commun., 2017,53, 11484-11487
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    Silver-mediated oxidative C–H difluoromethylation of phenanthridines and 1,10-phenanthrolines

    S. Zhu, X. Xu and F. Qing, Chem. Commun., 2017, 53, 11484
    DOI: 10.1039/C7CC05411D

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