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Issue 75, 2017
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A novel supramolecular magnesoborate framework with snowflake-like channels built by unprecedented huge B69 cluster cages

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Abstract

A novel magnesoborate, Mg7@[B69O108(OH)18], with a 3D supramolecular framework has been made under solvothermal conditions, and features wonderful snowflake-like channels assembled from unprecedented [B69O108(OH)18] clusters. Notably, unique triple-helical ribbons reside in the middle of the B69 cluster. Up to now, the discovery of a B69 cluster sets a new record in cluster sizes among borates.

Graphical abstract: A novel supramolecular magnesoborate framework with snowflake-like channels built by unprecedented huge B69 cluster cages

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Publication details

The article was received on 13 Jul 2017, accepted on 25 Aug 2017 and first published on 25 Aug 2017


Article type: Communication
DOI: 10.1039/C7CC05404A
Citation: Chem. Commun., 2017,53, 10398-10401
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    A novel supramolecular magnesoborate framework with snowflake-like channels built by unprecedented huge B69 cluster cages

    J. Wang and G. Yang, Chem. Commun., 2017, 53, 10398
    DOI: 10.1039/C7CC05404A

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