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Supramolecular five-component nano-oscillator

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Abstract

A five-component self-sorted metallo-supramolecular nano-oscillator was designed based on the full orthogonality of three different dynamic complexation motifs. The oscillating motion in the machinery, determined as 106 kHz at 25 °C by VT-NMR, arises due to dissociation/association of the pyridine terminal of the oscillator arm between two zinc(II) porphyrin stations.

Graphical abstract: Supramolecular five-component nano-oscillator

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Publication details

The article was received on 06 Jul 2017, accepted on 03 Aug 2017 and first published on 03 Aug 2017


Article type: Communication
DOI: 10.1039/C7CC05235A
Citation: Chem. Commun., 2017, Advance Article
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    Supramolecular five-component nano-oscillator

    D. Samanta, I. Paul and M. Schmittel, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC05235A

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