SCHEDULED MAINTENANCE
A five-component self-sorted metallo-supramolecular nano-oscillator was designed based on the full orthogonality of three different dynamic complexation motifs. The oscillating motion in the machinery, determined as 106 kHz at 25 °C by VT-NMR, arises due to dissociation/association of the pyridine terminal of the oscillator arm between two zinc(II) porphyrin stations.
D. Samanta, I. Paul and M. Schmittel, Chem. Commun., 2017, 53, 9709 DOI: 10.1039/C7CC05235A
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