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Issue 72, 2017
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Synthesis of borasiloxanes by oxidative hydrolysis of silanes and pinacolborane using Cu3(BTC)2 as a solid catalyst

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Abstract

A convenient method for the synthesis of borasiloxanes from silanes and pinacolboranes using Cu3(BTC)2 as a heterogeneous catalyst in acetonitrile at 70 °C is reported. This procedure is more convenient than Ru and Pd based homogeneous catalysts because it avoids the use of noble metals, easy handling of starting materials and the catalyst can be reused.

Graphical abstract: Synthesis of borasiloxanes by oxidative hydrolysis of silanes and pinacolborane using Cu3(BTC)2 as a solid catalyst

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Publication details

The article was received on 08 Jul 2017, accepted on 08 Aug 2017 and first published on 08 Aug 2017


Article type: Communication
DOI: 10.1039/C7CC05221A
Citation: Chem. Commun., 2017,53, 9998-10001
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    Synthesis of borasiloxanes by oxidative hydrolysis of silanes and pinacolborane using Cu3(BTC)2 as a solid catalyst

    A. Dhakshinamoorthy, A. M. Asiri, P. Concepcion and H. Garcia, Chem. Commun., 2017, 53, 9998
    DOI: 10.1039/C7CC05221A

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