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Iodoarene-catalyzed Oxidative Transformations Using Molecular Oxygen

Abstract

Molecular oxygen serves as a useful oxidant for glycol scission of 1,2-diols and Hofmann rearrangement of primary amides using pentamethyliodobenzene as a catalyst. Use of isobutyraldehyde and Lewis basic nitriles under O2 enabled iodine(I)/(III) catalytic cycle, where in situ-generated peracid acts as a terminal oxidant.

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Publication details

The article was received on 05 Jul 2017, accepted on 08 Aug 2017 and first published on 08 Aug 2017


Article type: Communication
DOI: 10.1039/C7CC05160C
Citation: Chem. Commun., 2017, Accepted Manuscript
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    Iodoarene-catalyzed Oxidative Transformations Using Molecular Oxygen

    K. Miyamoto, J. Yamashita, S. Narita, Y. Sakai, K. Hirano, T. Saito, C. WANG, M. Ochiai and U. Masanobu, Chem. Commun., 2017, Accepted Manuscript , DOI: 10.1039/C7CC05160C

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