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Migratory Insertion and Hydrogenation of a Bridging Azide in Thiolate-Bridged Dicobalt Reaction Platform

Abstract

A novel well-defined thiolate-bridged dicobalt azido complex converts to a rare sulfilimide-bridged dicobalt complex via nitrogen atom migratory insertion into the Co−S bond upon thermolysis. Intriguingly, the homolytic cleavage of hydrogen is achieved by this azide under mild conditions to furnish a partially hydrogenated azido complex.

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Publication details

The article was received on 01 Jul 2017, accepted on 10 Aug 2017 and first published on 10 Aug 2017


Article type: Communication
DOI: 10.1039/C7CC05092E
Citation: Chem. Commun., 2017, Accepted Manuscript
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    Migratory Insertion and Hydrogenation of a Bridging Azide in Thiolate-Bridged Dicobalt Reaction Platform

    Y. Zhang, P. Tong, D. Yang, J. Li, B. Wang and J. Qu, Chem. Commun., 2017, Accepted Manuscript , DOI: 10.1039/C7CC05092E

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