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Issue 71, 2017
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Migratory insertion and hydrogenation of a bridging azide in a thiolate-bridged dicobalt reaction platform

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Abstract

A novel well-defined thiolate-bridged dicobalt azido complex is converted to a rare sulfilimide-bridged dicobalt complex via nitrogen atom migratory insertion into the Co–S bond upon thermolysis. Intriguingly, the homolytic cleavage of hydrogen is achieved by this azide under mild conditions to furnish a partially hydrogenated azido complex.

Graphical abstract: Migratory insertion and hydrogenation of a bridging azide in a thiolate-bridged dicobalt reaction platform

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Publication details

The article was received on 01 Jul 2017, accepted on 10 Aug 2017 and first published on 10 Aug 2017


Article type: Communication
DOI: 10.1039/C7CC05092E
Citation: Chem. Commun., 2017,53, 9854-9857
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    Migratory insertion and hydrogenation of a bridging azide in a thiolate-bridged dicobalt reaction platform

    Y. Zhang, P. Tong, D. Yang, J. Li, B. Wang and J. Qu, Chem. Commun., 2017, 53, 9854
    DOI: 10.1039/C7CC05092E

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