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Issue 61, 2017
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Postsynthetic modification of a zirconium metal–organic framework at the inorganic secondary building unit with diphenylphosphinic acid for increased photosensitizing properties and stability

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Abstract

A zirconium metal–organic framework (MOF) PCN-222 was postsynthetically modified with diphenylphosphinic acid, resulting in an increased stability when activated from water and 4 times higher photosensitizing properties for singlet oxygen production. The phosphinic acid did not compromise the crystallinity of the MOF but made strong bonds with the zirconia secondary building units.

Graphical abstract: Postsynthetic modification of a zirconium metal–organic framework at the inorganic secondary building unit with diphenylphosphinic acid for increased photosensitizing properties and stability

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Publication details

The article was received on 30 Jun 2017, accepted on 06 Jul 2017 and first published on 06 Jul 2017


Article type: Communication
DOI: 10.1039/C7CC05068B
Citation: Chem. Commun., 2017,53, 8557-8560
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    Postsynthetic modification of a zirconium metal–organic framework at the inorganic secondary building unit with diphenylphosphinic acid for increased photosensitizing properties and stability

    J. Hynek, S. Ondrušová, D. Bůžek, P. Kovář, J. Rathouský and J. Demel, Chem. Commun., 2017, 53, 8557
    DOI: 10.1039/C7CC05068B

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