Issue 63, 2017

Post-synthetic transformation of a Zn(ii) polyhedral coordination network into a new supramolecular isomer of HKUST-1

Abstract

A Zn-based porphyrin containing metal–organic material (porphMOM-1) was transformed into a novel Cu-based porphyrin-encapsulating metal–organic material (porph@HKUST-1-β) via a one-pot post-synthetic modification (PSM) process involving both metal ion exchange and linker installation of trimesic acid. HKUST-1-β is the first example of yao topology and is to our knowledge the first supramolecular isomer of the archetypal coordination network HKUST-1.

Graphical abstract: Post-synthetic transformation of a Zn(ii) polyhedral coordination network into a new supramolecular isomer of HKUST-1

Supplementary files

Article information

Article type
Communication
Submitted
27 Jun 2017
Accepted
13 Jul 2017
First published
17 Jul 2017

Chem. Commun., 2017,53, 8866-8869

Post-synthetic transformation of a Zn(II) polyhedral coordination network into a new supramolecular isomer of HKUST-1

Y. Chen, L. Wojtas, S. Ma, M. J. Zaworotko and Z. Zhang, Chem. Commun., 2017, 53, 8866 DOI: 10.1039/C7CC04958G

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