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Issue 66, 2017
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Reversible photoreduction of Cu(II)–coumarin metal–organic polyhedra

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Abstract

We report a new approach for photoinduced reduction of Cu2+ that will enrich the structural diversity of coordination complexes and be a valuable contributor to the development of Cu+/Cu0-based catalysts. To realize controlled Cu2+ reduction, coumarin as a triplet quencher of excited benzophenone was tethered to Cu(II)–metal–organic polyhedra (MOPs). The photoinduced catalytic activity of the coumarin-MOPs was also examined in a Cu(I)-catalyzed azide–alkyne cycloaddition (CuAAC).

Graphical abstract: Reversible photoreduction of Cu(ii)–coumarin metal–organic polyhedra

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Publication details

The article was received on 20 Jun 2017, accepted on 26 Jul 2017 and first published on 26 Jul 2017


Article type: Communication
DOI: 10.1039/C7CC04799A
Citation: Chem. Commun., 2017,53, 9250-9253
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    Reversible photoreduction of Cu(II)–coumarin metal–organic polyhedra

    J. Bae, K. Baek, D. Yuan, W. Kim, K. Kim, H. Zhou and J. Park, Chem. Commun., 2017, 53, 9250
    DOI: 10.1039/C7CC04799A

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