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Issue 66, 2017
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B(C6F5)3-Promoted hydrogenations of N-heterocycles with ammonia borane

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Abstract

A transition-metal-free method for the B(C6F5)3-promoted hydrogenations of N-heterocycles using ammonia borane under mild reaction conditions has been developed. The reaction affords a broad range of hydrogenated products in moderate to good yields. The enantioselective versions for the corresponding products were also investigated via our approach, showing good feasibility.

Graphical abstract: B(C6F5)3-Promoted hydrogenations of N-heterocycles with ammonia borane

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Publication details

The article was received on 17 Jun 2017, accepted on 25 Jul 2017 and first published on 25 Jul 2017


Article type: Communication
DOI: 10.1039/C7CC04709F
Citation: Chem. Commun., 2017,53, 9262-9264
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    B(C6F5)3-Promoted hydrogenations of N-heterocycles with ammonia borane

    F. Ding, Y. Zhang, R. Zhao, Y. Jiang, R. L. Bao, K. Lin and L. Shi, Chem. Commun., 2017, 53, 9262
    DOI: 10.1039/C7CC04709F

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