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Issue 60, 2017
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Microwave induced “egg yolk” structure in Cr/V-MIL-53

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Abstract

Using a one pot microwave procedure, mixed-metal “egg yolk” MOFs are created, with a core of (Cr/V)-MIL-53 and a shell of Cr-MIL-53. In contrast, the solvothermal method produces homogeneous mixed-metal MOFs. The influence of Cr and V on the flexibility and breathing was studied via T-XRPD and CO2 adsorption measurements.

Graphical abstract: Microwave induced “egg yolk” structure in Cr/V-MIL-53

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Publication details

The article was received on 15 Jun 2017, accepted on 04 Jul 2017 and first published on 04 Jul 2017


Article type: Communication
DOI: 10.1039/C7CC04651K
Citation: Chem. Commun., 2017,53, 8478-8481
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    Microwave induced “egg yolk” structure in Cr/V-MIL-53

    H. Depauw, I. Nevjestić, J. De Winne, G. Wang, K. Haustraete, K. Leus, A. Verberckmoes, C. Detavernier, F. Callens, E. De Canck, H. Vrielinck and P. Van Der Voort, Chem. Commun., 2017, 53, 8478
    DOI: 10.1039/C7CC04651K

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