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Highly efficient Cr2O72− removal of a 3D metal-organic framework fabricated by tandem single-crystal to single-crystal transformations from a 1D coordination array

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Abstract

The single-crystal to single-crystal (SC–SC) transformation from a 1D coordination chain to a 3D coordination network, which is triggered by both solvent and anion exchanges, has been revealed to suffer from a tandem mechanism as proved by isolation of the intermediate state. The resulting porous crystalline material shows a high efficiency for the capture of dichromates (207 mg g−1) via the SC–SC anion-exchange.

Graphical abstract: Highly efficient Cr2O72− removal of a 3D metal-organic framework fabricated by tandem single-crystal to single-crystal transformations from a 1D coordination array

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Publication details

The article was received on 11 Jun 2017, accepted on 10 Jul 2017 and first published on 10 Jul 2017


Article type: Communication
DOI: 10.1039/C7CC04527A
Citation: Chem. Commun., 2017, Advance Article
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    Highly efficient Cr2O72− removal of a 3D metal-organic framework fabricated by tandem single-crystal to single-crystal transformations from a 1D coordination array

    C. Li, H. Zhou, S. Wang, J. Chen, Z. Wang and M. Du, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC04527A

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