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Issue 64, 2017
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Co-catalyzed highly selective C(sp3)–H nitration

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Abstract

A Co-catalyzed highly chemo- and regio-selective nitration of C(sp3)–H was developed. Diverse aliphatic nitro compounds were obtained in good yields, using t-BuONO as a nitrating reagent. Specific nitration of C(sp3)–H instead of C(sp2)–H was achieved via a radical process rather than concerted metalation–deprotonation.

Graphical abstract: Co-catalyzed highly selective C(sp3)–H nitration

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Publication details

The article was received on 08 Jun 2017, accepted on 10 Jul 2017 and first published on 10 Jul 2017


Article type: Communication
DOI: 10.1039/C7CC04433J
Citation: Chem. Commun., 2017,53, 8972-8975
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    Co-catalyzed highly selective C(sp3)–H nitration

    Y. Zhou, Z. Tang and Q. Song, Chem. Commun., 2017, 53, 8972
    DOI: 10.1039/C7CC04433J

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