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Issue 60, 2017
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A divergent [5+2] cascade approach to bicyclo[3.2.1]octanes: facile synthesis of ent-kaurene and cedrene-type skeletons

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Abstract

A solvent-dependent oxidative dearomatization-induced divergent [5+2] cascade approach to bicyclo[3.2.1]octanes was described. This novel protocol enables a facile synthesis of a series of diversely functionalized ent-kaurene and cedrene-type skeletons in good yields and excellent diastereoselectivities.

Graphical abstract: A divergent [5+2] cascade approach to bicyclo[3.2.1]octanes: facile synthesis of ent-kaurene and cedrene-type skeletons

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Publication details

The article was received on 03 Jun 2017, accepted on 05 Jul 2017 and first published on 05 Jul 2017


Article type: Communication
DOI: 10.1039/C7CC04292B
Citation: Chem. Commun., 2017,53, 8435-8438
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    A divergent [5+2] cascade approach to bicyclo[3.2.1]octanes: facile synthesis of ent-kaurene and cedrene-type skeletons

    C. He, Z. Bai, J. Hu, B. Wang, H. Xie, L. Yu and H. Ding, Chem. Commun., 2017, 53, 8435
    DOI: 10.1039/C7CC04292B

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