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Issue 77, 2017
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Isoreticular expansion of polyMOFs achieves high surface area materials

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Abstract

The concept of isoreticular chemistry has become a core principle in metal–organic framework (MOF) materials. Isoreticular chemistry has shown that organic ligands of different sizes, but with a common geometry/symmetry can be used to generate MOFs of related topologies, but with expanded pore sizes and volumes. In this report, polymer–MOF hybrid materials (polyMOFs) with a UiO (UiO = University of Oslo) architecture are shown to adhere to the principle of isoreticular expansion, generating polyMOFs with large surface areas and enhanced stability.

Graphical abstract: Isoreticular expansion of polyMOFs achieves high surface area materials

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Publication details

The article was received on 31 May 2017, accepted on 11 Sep 2017 and first published on 11 Sep 2017


Article type: Communication
DOI: 10.1039/C7CC04222A
Citation: Chem. Commun., 2017,53, 10684-10687
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    Isoreticular expansion of polyMOFs achieves high surface area materials

    G. E. M. Schukraft, S. Ayala, B. L. Dick and S. M. Cohen, Chem. Commun., 2017, 53, 10684
    DOI: 10.1039/C7CC04222A

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