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Adaptability of the metal(III,IV) 1,2,3-trioxobenzene rod secondary building unit for the production of chemically stable and catalytically active MOFs

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Abstract

The use of a 5,10,15,20-tetrakis(3,4,5-trihydroxyphenyl)porphyrin has yielded a new MOF based on M-1,2,3-trioxobenzene chains that can be made of M = Zr(IV) or RE(III) (RE = rare earth), showing a very high and limited chemical stability, respectively. The robust metallated Zr-analogue, Co-MIL-173(Zr), has proven to be a heme-like heterogeneous catalyst suitable for aerobic oxidation of hydrocarbons.

Graphical abstract: Adaptability of the metal(iii,iv) 1,2,3-trioxobenzene rod secondary building unit for the production of chemically stable and catalytically active MOFs

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Publication details

The article was received on 16 Apr 2017, accepted on 12 Jun 2017 and first published on 15 Jun 2017


Article type: Communication
DOI: 10.1039/C7CC04215A
Citation: Chem. Commun., 2017, Advance Article
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    Adaptability of the metal(III,IV) 1,2,3-trioxobenzene rod secondary building unit for the production of chemically stable and catalytically active MOFs

    G. Mouchaham, B. Abeykoon, M. Giménez-Marqués, S. Navalon, A. Santiago-Portillo, M. Affram, N. Guillou, C. Martineau, H. Garcia, A. Fateeva and T. Devic, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC04215A

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