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Issue 59, 2017
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An unprecedented trinuclear FeII triazole-based complex exhibiting a concerted and complete sharp spin transition above room temperature

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Abstract

We report a triazole-based trinuclear complex as the first example that displays a complete one-step first-order [HS–HS–HS] ↔ [LS–LS–LS] spin transition at 318 K. The strong ferro-elastic interactions, between the three metal centers, have been identified as the source of the concerted spin transition in this trinuclear complex.

Graphical abstract: An unprecedented trinuclear FeII triazole-based complex exhibiting a concerted and complete sharp spin transition above room temperature

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Publication details

The article was received on 27 May 2017, accepted on 30 Jun 2017 and first published on 30 Jun 2017


Article type: Communication
DOI: 10.1039/C7CC04112H
Citation: Chem. Commun., 2017,53, 8356-8359
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    An unprecedented trinuclear FeII triazole-based complex exhibiting a concerted and complete sharp spin transition above room temperature

    N. Pittala, F. Thétiot, C. Charles, S. Triki, K. Boukheddaden, G. Chastanet and M. Marchivie, Chem. Commun., 2017, 53, 8356
    DOI: 10.1039/C7CC04112H

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