A modular synthesis approach to multinuclear heterometallic oxo clusters in polyoxometalates

Takuo Minato; Kosuke Suzuki; Yusuke Ohata; Kazuya Yamaguchi; Noritaka Mizuno

doi:10.1039/C7CC04072E

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A modular synthesis approach to multinuclear heterometallic oxo clusters in polyoxometalates†

Takuo Minato,^a Kosuke Suzuki,

*^a Yusuke Ohata,^a Kazuya Yamaguchi

^a and Noritaka Mizuno*^a

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* Corresponding authors

^a Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan
E-mail: ksuzuki@appchem.t.u-tokyo.ac.jp, tmizuno@mail.ecc.u-tokyo.ac.jp
Fax: +81-3-5841-7220

Abstract

We report a “modular synthesis approach” to multinuclear heterometallic oxo clusters in lacunary polyoxometalates (POMs). This approach allowed the synthesis of a POM containing a nonanuclear {CrMn₄}Lu₂Ag₂ cluster with the widest variety of metals among the discrete metal oxo clusters prepared to date.

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DOI: https://doi.org/10.1039/C7CC04072E
Article type: Communication
Submitted: 26 May 2017
Accepted: 09 Jun 2017
First published: 12 Jun 2017

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Chem. Commun., 2017,53, 7533-7536

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A modular synthesis approach to multinuclear heterometallic oxo clusters in polyoxometalates

T. Minato, K. Suzuki, Y. Ohata, K. Yamaguchi and N. Mizuno, Chem. Commun., 2017, 53, 7533 DOI: 10.1039/C7CC04072E

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Chemical Communications

A modular synthesis approach to multinuclear heterometallic oxo clusters in polyoxometalates†

Abstract

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A modular synthesis approach to multinuclear heterometallic oxo clusters in polyoxometalates

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