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A modular synthesis approach to multinuclear heterometallic oxo clusters in polyoxometalates

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Abstract

We report a “modular synthesis approach” to multinuclear heterometallic oxo clusters in lacunary polyoxometalates (POMs). This approach allowed the synthesis of a POM containing a nonanuclear {CrMn4}Lu2Ag2 cluster with the widest variety of metals among the discrete metal oxo clusters prepared to date.

Graphical abstract: A modular synthesis approach to multinuclear heterometallic oxo clusters in polyoxometalates

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Publication details

The article was received on 26 May 2017, accepted on 09 Jun 2017 and first published on 12 Jun 2017


Article type: Communication
DOI: 10.1039/C7CC04072E
Citation: Chem. Commun., 2017, Advance Article
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    A modular synthesis approach to multinuclear heterometallic oxo clusters in polyoxometalates

    T. Minato, K. Suzuki, Y. Ohata, K. Yamaguchi and N. Mizuno, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC04072E

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