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Reversible Crystal-to-Crystal Transformation from Trinuclear Cluster to 1D Chain and Corresponding Spin Crossover (SCO) Behaviour Change

Abstract

Reversible crystal-to-crystal transformation between a linear trinuclear Fe(II) complexe [Fe3(NH2-trz)6(SCN)5(H2O)] (SCN)·4H2O (1, NH2-trz = 4-amino-1,2,4-triazole) and a 1D chain [Fe3(NH2-trz)6(SCN)5]n(SCN)n (1a) and the SCO behaviours change is studied by X-ray single-crystal diffraction, magnetic measurements and DSC. Complex 1a exhibits one more SCO step at low temperature.

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Publication details

The article was received on 25 May 2017, accepted on 19 Jun 2017 and first published on 19 Jun 2017


Article type: Communication
DOI: 10.1039/C7CC04036A
Citation: Chem. Commun., 2017, Accepted Manuscript
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    Reversible Crystal-to-Crystal Transformation from Trinuclear Cluster to 1D Chain and Corresponding Spin Crossover (SCO) Behaviour Change

    W. Chen, J. Leng, Z. Wang, Y. Chen, Y. Miao, M. Tong and W. Dong, Chem. Commun., 2017, Accepted Manuscript , DOI: 10.1039/C7CC04036A

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