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Issue 55, 2017
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Reversible crystal-to-crystal transformation from a trinuclear cluster to a 1D chain and the corresponding spin crossover (SCO) behaviour change

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Abstract

Reversible crystal-to-crystal transformation between a linear trinuclear Fe(II) complex [Fe3(NH2-trz)6(SCN)5(H2O)] (SCN)·4H2O (1, NH2-trz = 4-amino-1,2,4-triazole) and a 1D chain [Fe3(NH2-trz)6(SCN)5]n(SCN)n (1a) and the SCO behaviour change have been studied by X-ray single-crystal diffraction, magnetic measurements and DSC. Complex 1a exhibits one more SCO step at a low temperature.

Graphical abstract: Reversible crystal-to-crystal transformation from a trinuclear cluster to a 1D chain and the corresponding spin crossover (SCO) behaviour change

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Publication details

The article was received on 25 May 2017, accepted on 19 Jun 2017 and first published on 19 Jun 2017


Article type: Communication
DOI: 10.1039/C7CC04036A
Citation: Chem. Commun., 2017,53, 7820-7823
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    Reversible crystal-to-crystal transformation from a trinuclear cluster to a 1D chain and the corresponding spin crossover (SCO) behaviour change

    W. Chen, J. Leng, Z. Wang, Y. Chen, Y. Miao, M. Tong and W. Dong, Chem. Commun., 2017, 53, 7820
    DOI: 10.1039/C7CC04036A

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