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Issue 54, 2017
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An enantioselective cascade for simultaneous generation of five quaternary stereocenters from fully substituted enones

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Abstract

A highly enantioselective cascade reaction for the generation of five quaternary stereocenters in one-pot operation is reported for the first time in the history of organic synthesis. Cinchona-alkaloid derived hydrogen-bonding catalyst furnished structurally complex cascade products from simple substrates in excellent yields and stereoselectivities.

Graphical abstract: An enantioselective cascade for simultaneous generation of five quaternary stereocenters from fully substituted enones

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Publication details

The article was received on 24 May 2017, accepted on 15 Jun 2017 and first published on 15 Jun 2017


Article type: Communication
DOI: 10.1039/C7CC03995F
Citation: Chem. Commun., 2017,53, 7649-7652
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    An enantioselective cascade for simultaneous generation of five quaternary stereocenters from fully substituted enones

    S. Yang, G. M. Reddy, T. Wang, Y. Yeh, M. Wang and W. Lin, Chem. Commun., 2017, 53, 7649
    DOI: 10.1039/C7CC03995F

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