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Nucleophilic reactivity of copper(II)–alkylperoxo complexes

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Abstract

Copper(II)–alkylperoxo adducts, [Cu(CHDAP)(OOR)]+ (CHDAP = N,N′-dicyclohexyl-2,11-diaza[3,3](2,6)pyridinophane; R = C(CH3)2Ph and tBu), were prepared and characterized using various physicochemical methods. These are the first synthetic Cu(II)–alkylperoxo complexes that can perform aldehyde deformylation (i.e., nucleophilic reactivity) under the stoichiometric reaction conditions, which was confirmed by kinetic studies.

Graphical abstract: Nucleophilic reactivity of copper(ii)–alkylperoxo complexes

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Publication details

The article was received on 23 May 2017, accepted on 26 Jul 2017 and first published on 27 Jul 2017


Article type: Communication
DOI: 10.1039/C7CC03965D
Citation: Chem. Commun., 2017, Advance Article
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    Nucleophilic reactivity of copper(II)–alkylperoxo complexes

    B. Kim, D. Jeong and J. Cho, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC03965D

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