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Issue 61, 2017
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NHC-stabilized 1-hydrosilaimine: synthesis, structure and reactivity

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Abstract

A facile, straightforward synthesis of N-heterocyclic carbene (NHC)-stabilized 1-hydrosilaimine starting from a silicon(IV)-precursor is reported. It has been employed for the addition of an O–H bond of water under ambient conditions without any additional catalyst.

Graphical abstract: NHC-stabilized 1-hydrosilaimine: synthesis, structure and reactivity

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Publication details

The article was received on 20 May 2017, accepted on 06 Jul 2017 and first published on 06 Jul 2017


Article type: Communication
DOI: 10.1039/C7CC03912C
Citation: Chem. Commun., 2017,53, 8592-8595
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    NHC-stabilized 1-hydrosilaimine: synthesis, structure and reactivity

    D. Dhara, T. Vijayakanth, M. Kr. Barman, K. P. K. Naik, N. Chrysochos, C. B. Yildiz, R. Boomishankar, C. Schulzke, V. Chandrasekhar and A. Jana, Chem. Commun., 2017, 53, 8592
    DOI: 10.1039/C7CC03912C

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