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Thiol-reactive (co)polymer scaffolds comprising organic arsenical acrylamides

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Abstract

Novel, well-defined organic arsenical homopolymers (Đ = 1.10–1.40) have been synthesised via RAFT polymerisation. Copolymerisation of the As-functional monomer with dimethylacrylamide yielded non-toxic polymer scaffolds (Đ ≈ 1.10) that could be manipulated in response to pH and undergo sequential reduction and substitution in the presence of thiols including cysteine and glutathione.

Graphical abstract: Thiol-reactive (co)polymer scaffolds comprising organic arsenical acrylamides

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Publication details

The article was received on 19 May 2017, accepted on 06 Jul 2017 and first published on 06 Jul 2017


Article type: Communication
DOI: 10.1039/C7CC03880A
Citation: Chem. Commun., 2017, Advance Article
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    Thiol-reactive (co)polymer scaffolds comprising organic arsenical acrylamides

    C. Footman, P. A. J. M. de Jongh, J. Tanaka, R. Peltier, K. Kempe, T. P. Davis and P. Wilson, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC03880A

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