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Issue 64, 2017
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Platinum(II) photo-catalysis for highly selective difluoroalkylation reactions

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Abstract

The platinum(II) photo-catalyzed difluoroalkylation of cinnamic acids and alkynes for selective construction of E-,Z-difluoroalkyl alkenes and difluoroalkyl alkenyl iodides, respectively, were achieved under mild conditions. The high efficiency, good substrate scope and high selectivity altogether highlight the prospect of Pt(II) photocatalysts in visible-light-driven organic transformation reactions.

Graphical abstract: Platinum(ii) photo-catalysis for highly selective difluoroalkylation reactions

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Publication details

The article was received on 17 May 2017, accepted on 19 Jun 2017 and first published on 04 Jul 2017


Article type: Communication
DOI: 10.1039/C7CC03823B
Citation: Chem. Commun., 2017,53, 8948-8951
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    Platinum(II) photo-catalysis for highly selective difluoroalkylation reactions

    J. Zhong, C. Yang, X. Chang, C. Zou, W. Lu and C. Che, Chem. Commun., 2017, 53, 8948
    DOI: 10.1039/C7CC03823B

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