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Issue 59, 2017
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Autocatalytic dioxygen activation to produce an iron(V)-oxo complex without any reductants

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Abstract

An iron(V)-oxo complex with a tetraamido macrocyclic ligand, [(TAML)FeV(O)], was produced by reacting [(TAML)FeIII] with dioxygen without any electron source in acetone at 298 K. The autocatalytic mechanism of dioxygen activation for the formation of an iron(V)-oxo complex has been clarified based on the autocatalysis by radical chain initiators.

Graphical abstract: Autocatalytic dioxygen activation to produce an iron(v)-oxo complex without any reductants

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Publication details

The article was received on 14 May 2017, accepted on 30 Jun 2017 and first published on 03 Jul 2017


Article type: Communication
DOI: 10.1039/C7CC03742B
Citation: Chem. Commun., 2017,53, 8348-8351
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    Autocatalytic dioxygen activation to produce an iron(V)-oxo complex without any reductants

    M. Sankaralingam, Y. Lee, X. Lu, A. K. Vardhaman, W. Nam and S. Fukuzumi, Chem. Commun., 2017, 53, 8348
    DOI: 10.1039/C7CC03742B

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