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Issue 55, 2017
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Asymmetric radical alkylation of N-sulfinimines under visible light photocatalytic conditions

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Abstract

In this communication, a new photocatalytic strategy for the addition of alkyl-radical derivatives to N-sulfinimines with complete diastereoselectivity and moderate to good yields is presented. This is the first asymmetric photocatalytic addition to N-sulfinimines under visible light irradiation with smooth conditions and functional group tolerance.

Graphical abstract: Asymmetric radical alkylation of N-sulfinimines under visible light photocatalytic conditions

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Publication details

The article was received on 13 May 2017, accepted on 21 Jun 2017 and first published on 21 Jun 2017


Article type: Communication
DOI: 10.1039/C7CC03724D
Citation: Chem. Commun., 2017,53, 7764-7767
  • Open access: Creative Commons BY-NC license
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    Asymmetric radical alkylation of N-sulfinimines under visible light photocatalytic conditions

    A. F. Garrido-Castro, H. Choubane, M. Daaou, M. C. Maestro and J. Alemán, Chem. Commun., 2017, 53, 7764
    DOI: 10.1039/C7CC03724D

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