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Transforming a chemically labile [2+3] imine cage into a robust carbamate cage

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Abstract

The synthesis of a highly acid and base-stable shape-persistent porous carbamate cage is presented. This cage is stable even in hot (100 °C) 1 M hydrochloric acid (pH = 0) or in concentrated hydrochloric acid (pH = −1) at room temperature without decomposition.

Graphical abstract: Transforming a chemically labile [2+3] imine cage into a robust carbamate cage

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Publication details

The article was received on 12 May 2017, accepted on 07 Jul 2017 and first published on 07 Jul 2017


Article type: Communication
DOI: 10.1039/C7CC03677A
Citation: Chem. Commun., 2017, Advance Article
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    Transforming a chemically labile [2+3] imine cage into a robust carbamate cage

    X. Hu, W. Zhang, F. Rominger, I. Wacker, R. R. Schröder and M. Mastalerz, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC03677A

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