Jump to main content
Jump to site search


Visible-Light-Activated Rhodium Complex in Enantioselective Conjugate Addition of α-Amino Radicals with Michael Acceptors

Abstract

We report an efficient enantioselective conjugate addition of photogenerated α-amino radicals to Michael acceptors catalyzed by newly prepared chiral-at-metal rhodium complex. This protocol exhibits that a single Rh(III) complex can serve not only as Lewis acid but also as photoredox catalyst to control the stereoselectivity during the bond formation.

Back to tab navigation

Supplementary files

Publication details

The article was received on 14 May 2017, accepted on 16 Jun 2017 and first published on 16 Jun 2017


Article type: Communication
DOI: 10.1039/C7CC03650G
Citation: Chem. Commun., 2017, Accepted Manuscript
  •   Request permissions

    Visible-Light-Activated Rhodium Complex in Enantioselective Conjugate Addition of α-Amino Radicals with Michael Acceptors

    S. Lin, G. Sun and Q. Kang, Chem. Commun., 2017, Accepted Manuscript , DOI: 10.1039/C7CC03650G

Search articles by author

Spotlight

Advertisements