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Issue 47, 2017
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Formation of supramolecular hetero-triads by controlling the hydrogen bonding of conjugate bases with a diprotonated porphyrin based on electrostatic interaction

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Abstract

The thermodynamic stability of diprotonated saddle-distorted dodecaphenylporphyrin (H4DPP2+(X)2) was controlled by the hydrogen-bonding strength of conjugate bases (X) of strong acids (HX) or acids (R+-COOH) having positively charged moieties. The thermodynamic control of H4DPP2+(X)2 made it possible to achieve selective formation of supramolecular hetero-triads, H4DPP2+(X)(Cl).

Graphical abstract: Formation of supramolecular hetero-triads by controlling the hydrogen bonding of conjugate bases with a diprotonated porphyrin based on electrostatic interaction

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Publication details

The article was received on 10 May 2017, accepted on 17 May 2017 and first published on 19 May 2017


Article type: Communication
DOI: 10.1039/C7CC03635C
Citation: Chem. Commun., 2017,53, 6359-6362
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    Formation of supramolecular hetero-triads by controlling the hydrogen bonding of conjugate bases with a diprotonated porphyrin based on electrostatic interaction

    W. Suzuki, H. Kotani, T. Ishizuka, Y. Shiota, K. Yoshizawa and T. Kojima, Chem. Commun., 2017, 53, 6359
    DOI: 10.1039/C7CC03635C

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