Jump to main content
Jump to site search


Formation of supramolecular hetero-triads by controlling hydrogen bonding of conjugate bases with a diprotonated porphyrin based on electrostatic interaction

Abstract

Thermodynamic stability of diprotonated saddle-distorted dodecaphenylporphyrin (H4DPP2+(X–)2) was controlled by hydrogen-bonding strength of conjugate bases (X) of strong acids (HX) or acids (R+-COOH) having positively charged moieties. The thermodynamic control of H4DPP2+(X–)2 made it possible to achieve selective formation of supramolecular hetero-triads, H4DPP2+(X)(Cl).

Back to tab navigation
Please wait while Download options loads

Supplementary files

Publication details

The article was received on 10 May 2017, accepted on 17 May 2017 and first published on 19 May 2017


Article type: Communication
DOI: 10.1039/C7CC03635C
Citation: Chem. Commun., 2017, Accepted Manuscript
  •   Request permissions

    Formation of supramolecular hetero-triads by controlling hydrogen bonding of conjugate bases with a diprotonated porphyrin based on electrostatic interaction

    W. Suzuki, H. Kotani, T. Ishizuka, Y. Shiota, K. Yoshizawa and T. Kojima, Chem. Commun., 2017, Accepted Manuscript , DOI: 10.1039/C7CC03635C

Search articles by author