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Record-high thermal barrier of the relaxation of magnetization in the nitride clusterfullerene Dy2ScN@C80-Ih

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Abstract

The Dy-Sc nitride clusterfullerene Dy2ScN@C80-Ih exhibits slow relaxation of magnetization up to 76 K. Above 60 K, thermally-activated relaxation proceeds via the fifth-excited Kramers doublet with the energy of 1735 ± 21 K, which is the highest barrier ever reported for dinuclear lanthanide single molecule magnets.

Graphical abstract: Record-high thermal barrier of the relaxation of magnetization in the nitride clusterfullerene Dy2ScN@C80-Ih

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Publication details

The article was received on 08 May 2017, accepted on 15 Jun 2017 and first published on 16 Jun 2017


Article type: Communication
DOI: 10.1039/C7CC03580B
Citation: Chem. Commun., 2017, Advance Article
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    Record-high thermal barrier of the relaxation of magnetization in the nitride clusterfullerene Dy2ScN@C80-Ih

    D. S. Krylov, F. Liu, S. M. Avdoshenko, L. Spree, B. Weise, A. Waske, A. U. B. Wolter, B. Büchner and A. A. Popov, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC03580B

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