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Dissolution behaviour and activation of selenium in phosphonium based ionic liquids

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Abstract

The dissolution behaviour of grey selenium in phosphonium based ionic liquids (ILs) has been investigated for the first time by 31P and 77Se nuclear magnetic resonance (NMR) experiments. The investigations evidence the formation of trialkylphosphane selenides which can serve as a selenium reservoir in the subsequent formation of metal selenides.

Graphical abstract: Dissolution behaviour and activation of selenium in phosphonium based ionic liquids

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Publication details

The article was received on 08 May 2017, accepted on 14 Jun 2017 and first published on 14 Jun 2017


Article type: Communication
DOI: 10.1039/C7CC03564K
Citation: Chem. Commun., 2017, Advance Article
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    Dissolution behaviour and activation of selenium in phosphonium based ionic liquids

    T. Zhang, K. Schwedtmann, J. J. Weigand, T. Doert and M. Ruck, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC03564K

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