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Elongation of magnetic relaxation times in a single-molecule magnet through intermetallic interactions: a clamshell-type dinuclear terbium(III)-phthalocynaninato quadruple-decker complex

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Abstract

A clamshell-type terbium(III)-phthalocyaninato quadruple-decker complex was synthesized. Magnetic measurements revealed that Tb–Tb interactions caused an increase in the magnetic relaxation time and enhanced the SMM properties.

Graphical abstract: Elongation of magnetic relaxation times in a single-molecule magnet through intermetallic interactions: a clamshell-type dinuclear terbium(iii)-phthalocynaninato quadruple-decker complex

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Publication details

The article was received on 08 May 2017, accepted on 10 Jul 2017 and first published on 10 Jul 2017


Article type: Communication
DOI: 10.1039/C7CC03553E
Citation: Chem. Commun., 2017, Advance Article
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    Elongation of magnetic relaxation times in a single-molecule magnet through intermetallic interactions: a clamshell-type dinuclear terbium(III)-phthalocynaninato quadruple-decker complex

    Y. Horii, K. Katoh, B. K. Breedlove and M. Yamashita, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC03553E

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