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Going against the flow: Os(II)-to-Ru(II) energy transfer in rod-like polypyridyl chromophore

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Abstract

The judicious design of a unique mixed-metal Ru–Os molecular rod led to the first photoinduced energy transfer from osmium-to-ruthenium in a polypyridyl complex. The absorbed light is directed from the osmium metal center to the peripheral ruthenium moieties, where only the low energy luminescence from the heteroleptic ruthenium phen-hpp complex was observed.

Graphical abstract: Going against the flow: Os(ii)-to-Ru(ii) energy transfer in rod-like polypyridyl chromophore

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Publication details

The article was received on 07 May 2017, accepted on 02 Aug 2017 and first published on 02 Aug 2017


Article type: Communication
DOI: 10.1039/C7CC03541A
Citation: Chem. Commun., 2017, Advance Article
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    Going against the flow: Os(II)-to-Ru(II) energy transfer in rod-like polypyridyl chromophore

    B. Laramée-Milette and G. S. Hanan, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC03541A

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