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Issue 64, 2017
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Visible-light-induced thiotrifluoromethylation of terminal alkenes with sodium triflinate and benzenesulfonothioates

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Abstract

An unconventional reductive quenching cycle was developed to realize the visible-light-induced thiotrifluoromethylation of terminal alkenes. CF3SO2Na was used as an easy to handle CF3 radical source to afford the desired products in moderate to good yields. Mild reaction conditions and a broad substrate scope feature in this transformation.

Graphical abstract: Visible-light-induced thiotrifluoromethylation of terminal alkenes with sodium triflinate and benzenesulfonothioates

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Publication details

The article was received on 06 May 2017, accepted on 06 Jul 2017 and first published on 07 Jul 2017


Article type: Communication
DOI: 10.1039/C7CC03520A
Citation: Chem. Commun., 2017,53, 8968-8971
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    Visible-light-induced thiotrifluoromethylation of terminal alkenes with sodium triflinate and benzenesulfonothioates

    W. Kong, H. An and Q. Song, Chem. Commun., 2017, 53, 8968
    DOI: 10.1039/C7CC03520A

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