Jump to main content
Jump to site search

Issue 58, 2017
Previous Article Next Article

Aluminum(I) β-diketiminato complexes activate C(sp2)–F and C(sp3)–F bonds by different oxidative addition mechanisms: a DFT study

Author affiliations

Abstract

DFT computations reveal different reaction mechanisms for the oxidative addition of C(sp2)–F and C(sp3)–F bonds to the Al(I) complexes: a concerted mechanism for C(sp2)–F and a stepwise mechanism for C(sp3)–F involving fluoride transfer and the formation and recombination of an ion pair.

Graphical abstract: Aluminum(i) β-diketiminato complexes activate C(sp2)–F and C(sp3)–F bonds by different oxidative addition mechanisms: a DFT study

Back to tab navigation

Supplementary files

Publication details

The article was received on 05 May 2017, accepted on 28 Jun 2017 and first published on 06 Jul 2017


Article type: Communication
DOI: 10.1039/C7CC03503A
Citation: Chem. Commun., 2017,53, 8196-8198
  •   Request permissions

    Aluminum(I) β-diketiminato complexes activate C(sp2)–F and C(sp3)–F bonds by different oxidative addition mechanisms: a DFT study

    C. E. Pitsch and X. Wang, Chem. Commun., 2017, 53, 8196
    DOI: 10.1039/C7CC03503A

Search articles by author

Spotlight

Advertisements