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Issue 58, 2017
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The first porphyrin–salen based chiral metal–organic framework for asymmetric cyanosilylation of aldehydes

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Abstract

The first porphyrin–salen based chiral metal–organic framework (ps-CMOF) constructed by judiciously incorporating metalloporphyrin and metallosalen struts into one MOF structure is reported, which can serve as an effective heterogeneous catalyst for the asymmetric cyanosilylation of aldehydes owing to the synergistic function between Lewis acid activation (from metalloporphyrin) and chiral induction (from metallosalen).

Graphical abstract: The first porphyrin–salen based chiral metal–organic framework for asymmetric cyanosilylation of aldehydes

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Publication details

The article was received on 05 May 2017, accepted on 27 Jun 2017 and first published on 27 Jun 2017


Article type: Communication
DOI: 10.1039/C7CC03499G
Citation: Chem. Commun., 2017,53, 8223-8226
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    The first porphyrin–salen based chiral metal–organic framework for asymmetric cyanosilylation of aldehydes

    J. Li, Y. Ren, C. Qi and H. Jiang, Chem. Commun., 2017, 53, 8223
    DOI: 10.1039/C7CC03499G

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