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Issue 57, 2017
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Monoradical-containing four-coordinate Co(III) complexes: homolytic S–S and Se–Se bond cleavage and catalytic isocyanate to urea conversion under sunlight

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Abstract

Four-coordinate, monoradical-containing Co(III) complexes participated in the non-innocent ligand driven homolytic cleavage of S–S and Se–Se bonds and catalyzed the conversion of RNCO (R = phenyl and naphthyl) to the corresponding urea derivatives (TON 480) in dry CH2Cl2 under sunlight stimulus.

Graphical abstract: Monoradical-containing four-coordinate Co(iii) complexes: homolytic S–S and Se–Se bond cleavage and catalytic isocyanate to urea conversion under sunlight

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Publication details

The article was received on 05 May 2017, accepted on 20 Jun 2017 and first published on 20 Jun 2017


Article type: Communication
DOI: 10.1039/C7CC03486E
Citation: Chem. Commun., 2017,53, 8022-8025
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    Monoradical-containing four-coordinate Co(III) complexes: homolytic S–S and Se–Se bond cleavage and catalytic isocyanate to urea conversion under sunlight

    G. C. Paul, S. Ghorai and C. Mukherjee, Chem. Commun., 2017, 53, 8022
    DOI: 10.1039/C7CC03486E

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