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Issue 51, 2017
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Thermal ring-opening polymerization of an unsymmetrical silicon-bridged [1]ferrocenophane in coordination nanochannels

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Abstract

Thermal ring-opening polymerization of the unsymmetrically substituted [1]ferrocenophane was performed in one-dimensional nanochannels of porous coordination polymers (PCPs). In contrast to conventional thermal polymerization in bulk, formation of cyclic polymer was inhibited in the channels. In addition, the tacticity of the resulting polymer was dependent on the pore size of PCPs.

Graphical abstract: Thermal ring-opening polymerization of an unsymmetrical silicon-bridged [1]ferrocenophane in coordination nanochannels

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Publication details

The article was received on 02 May 2017, accepted on 06 Jun 2017 and first published on 06 Jun 2017


Article type: Communication
DOI: 10.1039/C7CC03391E
Citation: Chem. Commun., 2017,53, 6945-6948
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    Thermal ring-opening polymerization of an unsymmetrical silicon-bridged [1]ferrocenophane in coordination nanochannels

    Y. Kobayashi, K. Honjo, S. Kitagawa, J. Gwyther, I. Manners and T. Uemura, Chem. Commun., 2017, 53, 6945
    DOI: 10.1039/C7CC03391E

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