Jump to main content
Jump to site search

Issue 51, 2017
Previous Article Next Article

A dielectric anomaly observed for doubly reduced mixed-valence polyoxometalate

Author affiliations

Abstract

Benzimidazolium is revealed to form quasi-isostructural crystals of mixed-valence molecular metal oxides that consist of [PMoV2MoVI10O40]5− and fully oxidized [BWVI12O40]5−. The structure and dielectric behaviour were compared and a dielectric anomaly was evident due to the electric dipole relaxation in the mixed-valence system.

Graphical abstract: A dielectric anomaly observed for doubly reduced mixed-valence polyoxometalate

Back to tab navigation

Supplementary files

Publication details

The article was received on 01 May 2017, accepted on 25 May 2017 and first published on 02 Jun 2017


Article type: Communication
DOI: 10.1039/C7CC03361C
Citation: Chem. Commun., 2017,53, 6824-6827
  •   Request permissions

    A dielectric anomaly observed for doubly reduced mixed-valence polyoxometalate

    I. Nakamura, R. Tsunashima, S. Nishihara, K. Inoue and T. Akutagawa, Chem. Commun., 2017, 53, 6824
    DOI: 10.1039/C7CC03361C

Search articles by author

Spotlight

Advertisements