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Issue 54, 2017
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Functionalised cyclodextrin-based metal–organic frameworks

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Abstract

CD-MOF, an extended framework incorporating the C8 symmetric cyclic oligosaccharide, γ-cyclodextrin (γ-CD), is based on the coordination of alkali metal cations to alternating α-1,4-linked D-glucopyranosyl units on the primary and secondary faces of the γ-CD tori. Here, we report the synthesis and characterisation of an amino-functionalised CD-MOF that is isostructural with pristine CD-MOF and adsorbs CO2 permanently.

Graphical abstract: Functionalised cyclodextrin-based metal–organic frameworks

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Publication details

The article was received on 29 Apr 2017, accepted on 13 Jun 2017 and first published on 13 Jun 2017


Article type: Communication
DOI: 10.1039/C7CC03345A
Citation: Chem. Commun., 2017,53, 7561-7564
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    Functionalised cyclodextrin-based metal–organic frameworks

    K. J. Hartlieb, A. W. Peters, T. C. Wang, P. Deria, O. K. Farha, J. T. Hupp and J. F. Stoddart, Chem. Commun., 2017, 53, 7561
    DOI: 10.1039/C7CC03345A

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