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Issue 46, 2017
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Click Co sandwich-terminated dendrimers as polyhydride reservoirs and micellar templates

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Abstract

Neutral click metallodendrimers with [CoI4-cyclopentadiene)(η5-cyclopentadienyl)] termini are synthesized by reduction of dendrimers with 9, 27 or 81 cobalticenium termini and serve as polyhydride reservoirs and reductants; for instance, they reduce proton sources to H2 and AuIII to micellized capsules of gold nanoparticles.

Graphical abstract: Click Co sandwich-terminated dendrimers as polyhydride reservoirs and micellar templates

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Publication details

The article was received on 28 Apr 2017, accepted on 19 May 2017 and first published on 19 May 2017


Article type: Communication
DOI: 10.1039/C7CC03311G
Citation: Chem. Commun., 2017,53, 6267-6270
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    Click Co sandwich-terminated dendrimers as polyhydride reservoirs and micellar templates

    A. Rapakousiou, C. Belin, L. Salmon, J. Ruiz and D. Astruc, Chem. Commun., 2017, 53, 6267
    DOI: 10.1039/C7CC03311G

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