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Issue 51, 2017
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Palladium-catalyzed intermolecular carbonylative cross-coupling of heteroaryl C(sp2)–H bonds with amines: an efficient strategy for oxidative aminocarbonylation of azoles

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Abstract

An efficient palladium-catalyzed oxidative aminocarbonylation of azoles has been developed. This system allows for intermolecular carbonylative cross-coupling of aromatic C(sp2)–H bonds with simple amines, which has often been asked for, but has not been realized so far. It provides a straightforward approach to a variety of azol-2-amides.

Graphical abstract: Palladium-catalyzed intermolecular carbonylative cross-coupling of heteroaryl C(sp2)–H bonds with amines: an efficient strategy for oxidative aminocarbonylation of azoles

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Publication details

The article was received on 27 Apr 2017, accepted on 07 Jun 2017 and first published on 07 Jun 2017


Article type: Communication
DOI: 10.1039/C7CC03274A
Citation: Chem. Commun., 2017,53, 6914-6917
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    Palladium-catalyzed intermolecular carbonylative cross-coupling of heteroaryl C(sp2)–H bonds with amines: an efficient strategy for oxidative aminocarbonylation of azoles

    Q. Xing, H. Lv, C. Xia and F. Li, Chem. Commun., 2017, 53, 6914
    DOI: 10.1039/C7CC03274A

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