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Issue 58, 2017
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A thermodynamic and kinetic analysis of solvent-enhanced selectivity in monophasic and biphasic reactor systems

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Abstract

Selectivity control in biomass conversion is often realized by manipulating the solvent environment. Outcomes can be rationalized through a thermodynamically rigorous application of transition-state theory. We show that solvent-induced perturbations to selectivity in both monophasic and biphasic reactor systems are governed by the same underlying principles.

Graphical abstract: A thermodynamic and kinetic analysis of solvent-enhanced selectivity in monophasic and biphasic reactor systems

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Publication details

The article was received on 25 Apr 2017, accepted on 26 Jun 2017 and first published on 27 Jun 2017


Article type: Communication
DOI: 10.1039/C7CC03164E
Citation: Chem. Commun., 2017,53, 8148-8151
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    A thermodynamic and kinetic analysis of solvent-enhanced selectivity in monophasic and biphasic reactor systems

    T. J. Schwartz and J. Q. Bond, Chem. Commun., 2017, 53, 8148
    DOI: 10.1039/C7CC03164E

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