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Transition-metal-free synthesis of β-trifluoromethylated enamines with trifluoromethanesulfinate

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Abstract

We have developed a transition-metal free trifluoromethylation protocol between enamines and CF3SO2Na. A wide range of β-trifluoromethyl substituted enamines were delivered in moderate to high yields with only E-configurations.

Graphical abstract: Transition-metal-free synthesis of β-trifluoromethylated enamines with trifluoromethanesulfinate

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Publication details

The article was received on 24 Apr 2017, accepted on 09 Jun 2017 and first published on 12 Jun 2017


Article type: Communication
DOI: 10.1039/C7CC03125D
Citation: Chem. Commun., 2017, Advance Article
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    Transition-metal-free synthesis of β-trifluoromethylated enamines with trifluoromethanesulfinate

    H. Jiang, W. Huang, Y. Yu, S. Yi, J. Li and W. Wu, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC03125D

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