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Issue 43, 2017
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Green and rapid synthesis of zirconium metal–organic frameworks via mechanochemistry: UiO-66 analog nanocrystals obtained in one hundred seconds

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Abstract

A UiO-66 analog was synthesized in 100 s using water-assisted grinding. The linker solubility suggested that tetrafluorobenzene-1,4-dicarboxylic acid was the best linker. Zr–metal–organic framework nanocrystals displayed good topologies and hydrophobicities, and high water/thermal stabilities. The less amorphous complex led to higher porosities and pore volumes with a 60 min grinding time.

Graphical abstract: Green and rapid synthesis of zirconium metal–organic frameworks via mechanochemistry: UiO-66 analog nanocrystals obtained in one hundred seconds

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Publication details

The article was received on 22 Apr 2017, accepted on 28 Apr 2017 and first published on 28 Apr 2017


Article type: Communication
DOI: 10.1039/C7CC03105J
Citation: Chem. Commun., 2017,53, 5818-5821
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    Green and rapid synthesis of zirconium metal–organic frameworks via mechanochemistry: UiO-66 analog nanocrystals obtained in one hundred seconds

    Y. Huang, W. Lo, Y. Kuo, W. Chen, C. Lin and F. Shieh, Chem. Commun., 2017, 53, 5818
    DOI: 10.1039/C7CC03105J

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