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A more critical role for silicon in the catalytic Staudinger amidation: silanes as non-innocent reductants

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Abstract

A revised pathway for the catalytic Staudinger amidation reaction is presented that involves the intervention of in situ-generated silyl esters as the species responsible for amidation.

Graphical abstract: A more critical role for silicon in the catalytic Staudinger amidation: silanes as non-innocent reductants

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Publication details

The article was received on 21 Apr 2017, accepted on 15 May 2017 and first published on 19 May 2017


Article type: Communication
DOI: 10.1039/C7CC03076B
Citation: Chem. Commun., 2017, Advance Article
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    A more critical role for silicon in the catalytic Staudinger amidation: silanes as non-innocent reductants

    K. G. Andrews and R. M. Denton, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC03076B

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