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Rh(III)-Catalyzed bilateral cyclization of aldehydes with nitrosos toward unsymmetrical acridines proceeding with C–H functionalization enabled by a transient directing group

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Abstract

A Rh(III)-catalyzed bilateral cyclization was developed for the efficient construction of acridines proceeding with C–H functionalization whereby in situ formation and removal of an imino transient directing group in the presence of catalytic amount of BnNH2 are achieved. In this transformation, a sequential Rh(III)-catalyzed C–H amination, cyclization, and aromatization process was involved.

Graphical abstract: Rh(iii)-Catalyzed bilateral cyclization of aldehydes with nitrosos toward unsymmetrical acridines proceeding with C–H functionalization enabled by a transient directing group

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Publication details

The article was received on 19 Apr 2017, accepted on 17 May 2017 and first published on 17 May 2017


Article type: Communication
DOI: 10.1039/C7CC03006A
Citation: Chem. Commun., 2017, Advance Article
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    Rh(III)-Catalyzed bilateral cyclization of aldehydes with nitrosos toward unsymmetrical acridines proceeding with C–H functionalization enabled by a transient directing group

    W. Hu, Q. Zheng, S. Sun and J. Cheng, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C7CC03006A

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