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Issue 47, 2017
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[Ge5Ni2(CO)3]2−: the first functionalized cluster of closo-[Ge5]2−

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Abstract

A new functionalized cluster, [Ge5Ni2(CO)3]2−, derived from the closo-[E5]2− (E = Si–Pb) anions which have been known for decades but whose reactivity has rarely been studied, was successfully isolated from the reaction of [Ni(PPh3)2(CO)2] and [Ge5]2− in ethylenediamine (en) solution, and its formation pathway was also investigated.

Graphical abstract: [Ge5Ni2(CO)3]2−: the first functionalized cluster of closo-[Ge5]2−

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Publication details

The article was received on 16 Apr 2017, accepted on 16 May 2017 and first published on 19 May 2017


Article type: Communication
DOI: 10.1039/C7CC02917A
Citation: Chem. Commun., 2017,53, 6315-6318
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    [Ge5Ni2(CO)3]2−: the first functionalized cluster of closo-[Ge5]2−

    C. Liu, L. Li, Q. Pan and Z. Sun, Chem. Commun., 2017, 53, 6315
    DOI: 10.1039/C7CC02917A

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