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[Ge5Ni2(CO)3]2-:The first functionalized cluster of closo-[Ge5]2−

Abstract

A new functionalized cluster [Ge5Ni2(CO)3]2−, derived from the closo-[E5]2− (E = Si-Pb) anions that have been known for decades but rarely studied on reactivity, was successfully isolated from the reaction of [Ni(PPh3)2(CO)2] and [Ge5]2− in ethylenediamine solution, and its formation mechanism was also investigated.

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Publication details

The article was received on 16 Apr 2017, accepted on 16 May 2017 and first published on 19 May 2017


Article type: Communication
DOI: 10.1039/C7CC02917A
Citation: Chem. Commun., 2017, Accepted Manuscript
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    [Ge5Ni2(CO)3]2-:The first functionalized cluster of closo-[Ge5]2−

    Z. Sun, C. Liu, L. Li and Q. Pan, Chem. Commun., 2017, Accepted Manuscript , DOI: 10.1039/C7CC02917A

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